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Abstract. We report the results of amino acid racemization (AAR) analyses of aspartic acid (Asp)and glutamic acid (Glu) in the planktic Neogloboquadrina pachyderma, and the benthic Cibicidoides wuellerstorfi, foraminifera species collected from sediment cores from the Arctic Ocean. The cores were retrieved at various deep-sea sites of the Arctic, which cover a large geographical area from the Greenland and Iceland seas (GIS) to the Alpha and Lomonosov ridges in the central Arctic Ocean. Age models for the investigated sediments were developed by multiple dating and correlation techniques, including oxygen isotope stratigraphy, magnetostratigraphy, biostratigraphy, lithostratigraphy, and cyclostratigraphy. The extent of racemization (D/L values) was determined on 95 samples (1028 subsamples) and shows a progressive increase downcore for both foraminifera species. Differences in the rates of racemization between the species were established by analysing specimens of both species from the same stratigraphic levels (n=21). Aspartic acid (Asp) and glutamic acid (Glu) racemize on average 16 ± 2 % and 23 ± 3 % faster, respectively, in C. wuellerstorfi than in N. pachyderma. The D/L values increase with sample age in nearly all cases, with a trend that follows a simple power function. Scatter around least-squares regression fits are larger for samples from the central Arctic Ocean than for those from the Nordic Seas. Calibrating the rate of racemization in C. wuellerstorfi using independently dated samples from the Greenland and Iceland seas for the past 400 ka enables estimation of sample ages from the central Arctic Ocean, where bottom water temperatures are presently relatively similar. The resulting ages are older than expected when considering the existing age models for the central Arctic Ocean cores. These results confirm that the differences are not due to taxonomic effects on AAR and further warrant a critical evaluation of existing Arctic Ocean age models. A better understanding of temperature histories at the investigated sites, and other environmental factors that may influence racemization rates in central Arctic Ocean sediments, is also needed.

 

We investigated the relationship between aspartic acid d:l ratios and otolith-derived age estimates in Gulf of Mexico red snapper, Lutjanus campechanus (ages 1–26 years; R² = 0.89) and Caribbean yellowtail snapper, Ocyurus chrysurus (ages 2–17 years; R² = 0.84). The estimated racemization rate was 0.61 × 10⁻³ year⁻¹for red snapper and 1.28 × 10⁻³ year⁻¹for yellowtail snapper, reflecting temperature differences between study regions. Mean jackknifed error in ages predicted from aspartic acid d:l was 1.70 ± 0.39 years for red snapper and 1.57 ± 0.41 years for yellowtail snapper. Results suggest amino acid racemization may be an effective tool for direct age estimation and potentially age validation in fishes.

 

Surficial shell accumulations from shallow marine settings are typically averaged over centennial-to-millennial time scales and dominated by specimens that died in the most recent centuries, resulting in strongly right-skewed age-frequency distributions (AFDs). However, AFDs from modern offshore settings (outer shelf and uppermost continental slope) still need to be explored. Using individually dated shells (14C-calibrated amino acid racemization), we compared AFDs along an onshore-offshore gradient across the southern Brazilian shelf, with sites ranging from the inner shelf, shallow-water (< 40 m) to offshore, deep-water (> 100 m) settings. The duration of time averaging is slightly higher in deeper water environments, and the AFD shapes change along the depositional profile. The inner shelf AFDs are strongly right-skewed due to the dominance of shells from the most recent millennia (median age range: 0–3 ka). In contrast, on the outer shelf and the uppermost continental slope, AFDs are symmetrical to left-skewed and dominated by specimens that died following the Last Glacial Maximum (median age range: 15–18 ka). The onshore-offshore changes in the observed properties of AFDs—increased median age and decreased skewness, but only slightly increased temporal mixing—likely reflect changes in sea level and concurrent water depth-related changes in biological productivity. These results suggest that on a passive continental margin subject to post-glacial sea-level changes, the magnitude of time-averaging of shell assemblages is less variable along the depositional profile than shell assemblage ages and the shapes of AFDs.

 

Death assemblages (DAs) are increasingly recognized as a valuable source to reconstruct past ecological baselines, due to the accumulation of skeletal material of non-contemporaneous cohorts. We here quantify the age and time-averaging of DAs on shallow subtidal (5–25 m) rocky substrates and in meadows ofPosidonia oceanicain the eastern Mediterranean. We show that such DAs are very young – median ages 9–56 years – with limited time-averaging, one to two orders of magnitude less than on even nearby soft substrates. On rocky substrates, out-of-habitat transport is likely the main cause of loss of older shells. InPosidonia oceanicameadows, the root and rhizome system creates a dense structure – thematte– that quickly entangles and buries shells and limits the potential for bioturbation. Thematteis, however, a peculiar feature ofPosidonia oceanica, and age and time-averaging in meadows of other seagrass species may be different. The young age of DAs in these habitats requires a careful consideration of their appropriateness as baselines. The large difference in DA age between soft substrates, subject to numerous studies, and hard and seagrass substrates, rarely inspected with geochronological techniques, implies that DA dating is important for studies aiming at using DAs as baselines.

 

Abstract. In 2013, the Intergovernmental Panel on Climate Changeconcluded that Northern Hemisphere temperatures had reached levelsunprecedented in at least 1400 years. The 2021 report now sees global meantemperatures rising to levels unprecedented in over 100 000 years. ThisTechnical Note briefly explains the reasons behind this major change.Namely, the new assessment reflects additional global warming that occurredbetween the two reports and improved paleotemperature reconstructions thatextend further back in time. In addition to past and recent warming, theconclusion also considers multi-century future warming, which therebyenables a direct comparison with paleotemperature reconstructions onmulti-century time scales. 

Major shifts in hydroclimate have been documented during the last deglacial period and the Holocene in south‐central Alaska. Rare freshwater calcium carbonate (marl) deposits in lakes on the Kenai Peninsula can be used to reconstruct past changes in hydroclimate, including the influence of groundwater inflow to lakes. Here, the postglacial sediment sequence from groundwater‐fed Kelly Lake (60.514°N, 150.374°W) was analyzed for multiple proxies including isotopes of carbon and oxygen in marl calcite (δ¹³C_marland δ¹⁸O_marl), and isotopes of carbon (ẟ¹³C_OM) and abundances of C and N in organic matter. Bulk sediment analyses include organic matter and calcium carbonate (CaCO₃) contents, visual stratigraphy and sediment flux. These analyses extend those of a previous paleoenvironmental reconstruction from Kelly Lake, which focused on sedimentary diatom oxygen isotopes and mass balance modeling over the past 10 000 years. Here, we show that Kelly Lake was deglaciated prior to 14.6 ka, and that by 14.0 ka marl dominated the sediments, with CaCO₃precipitation probably driven by groundwater input and mediated by shallow‐water charophytes. Marl accumulation decreased as organic and clastic inputs increased between ~12.2 and 11.5 ka. This shift, together with an increase in both δ¹³C_marland δ¹⁸O_marlvalues and a decrease in CaCO₃content, indicates an increase in the influence of meteoric water on the hydrologic budget under wet conditions, possibly driven by a strengthened Aleutian Low atmospheric pressure cell. A shift to lower δ¹³C_marland δ¹⁸O_marlvalues at ~11.5 ka is interpreted as an increase in the proportion of groundwater relative to meteoric water in the lake. Beginning around 9 ka, the proportion of meteoric water input continued to increase, the surrounding coniferous forest was established, and by 8 ka, CaCO₃accumulation ended. Our results elucidate the environmental conditions under which marl was deposited during the Lateglacial and early Holocene in this part of Alaska, and demonstrate how a variety of synoptic‐ and local‐scale climatic variables can converge to influence sedimentation in a groundwater‐fed lake.

 

Lake‐based studies can provide seasonal‐ to millennial‐scale records of sediment yield to improve our understanding of catchment‐scale sediment transfer and complement shorter fluvial‐based sediment transport studies. In this study, sediment accumulation rates at 40 coring locations in Lake Peters, Brooks Range, Alaska, over ca. 42 years, calculated using fallout radionuclides and sediment density patterns, were spatially modelled based on distance from the primary inflow and lake water depth. We estimated mean interdecadal specific sediment yield (Mg km⁻² year⁻¹) using the spatially modelled sediment accumulation rates and compared that result to fluvial‐based sediment delivery for 2015–2016 open‐channel seasons, as well as to yields reported for other Arctic catchments. Using the lake‐based method, mean yield to Lake Peters between ca. 1973 and 2015 was 52 ± 12 Mg km⁻² year⁻¹, which is comparable with fluvial‐based modelling results of 33 (20–60) Mg km⁻² year⁻¹in 2015 and 79 (50–140) Mg km⁻² year⁻¹in 2016 (95% confidence intervals), respectively. Although 2016 was a year of above average sedimentation, the last extreme depositional event probably occurred between ca. 1970 and 1976 when a basal layer of fine sand was deposited in a broadly distributed, relatively thick and coarse bed, which we used for lake‐wide correlation. The dual lacustrine–fluvial method approach permits study of within‐lake and catchment‐scale processes. Within Lake Peters, sedimentation patterns show decreasing fluxes down‐lake, sediment bypassing near the primary inflow, the influence of secondary inflows and littoral redistribution, and a focusing effect in the deep proximal basin. At the watershed scale, sediment yield is largely driven by intense summer rainfall and strong seasonal hydroclimatic variability. This research informs paleo‐environmental reconstruction and environmental system modelling in Arctic lake catchments.

 

Recent decades of warmer climate have brought drying wetlands and falling lake levels to southern Alaska. These recent changes can be placed into a longer-term context of postglacial lake-level fluctuations that include low stands that were as much as 7 m lower than present at eight lakes on the Kenai Lowland. Closed-basin lakes on the Kenai Lowland are typically ringed with old shorelines, usually as wave-cut scarps, cut several meters above modern lake levels; the scarps formed during deglaciation at 25–19 ka in a kettle moraine topography on the western Kenai Lowland. These high-water stands were followed by millennia of low stands, when closed-basin lake levels were drawn down by 5–10 m or more. Peat cores from satellite fens near or adjoining the eight closed-basin lakes show that a regional lake level rise was underway by at least 13.4 ka. At Jigsaw Lake, a detailed study of 23 pairs of overlapping sediment cores, seismic profiling, macrofossil analysis, and 58 AMS radiocarbon dates reveal rapidly rising water levels at 9–8 ka that caused large slabs of peat to slough off and sink to the lake bottom. These slabs preserve an archive of vegetation that had accumulated on a lakeshore apron exposed during the preceding drawdown period. They also preserve evidence of a brief period of lake level rise at 4.7–4.5 ka. We examined plant succession using in situ peat sequences in nine satellite fens around Jigsaw Lake that indicated increased effective moisture between 4.6 and 2.5 ka synchronous with the lake level rise. Mid- to late-Holocene lake high stands in this area are recorded by numerous ice-shoved ramparts (ISRs) along the shores. ISRs at 15 lakes show that individual ramparts typically record several shove events, separated by hundreds or thousands of years. Most ISRs date to within the last 5200 years and it is likely that older ISRs were erased by rising lake levels during the mid- to late Holocene. This study illustrates how data on vegetation changes in hydrologically coupled satellite-fen peat records can be used to constrain the water level histories in larger adjacent lakes. We suggest that this method could be more widely utilized for paleo-lake level reconstruction.